Sodium is a metal as it have 1 electron to complete it's valance shell, conduct electricity and have lower electronegativities . Electronegativity is a measure of the ability of an atom in a molecule to draw bonding electrons to itself.
Electronegativity information and above picture are from :
http://hyperphysics.phy-astr.gsu.edu/hbase/pertab/metal.html
http://hyperphysics.phy-astr.gsu.edu/hbase/chemical/bondd.html#c3
Sulfur is a non-metal as it gain 2 electrons to complete it's valance shell, does not conduct electricity and have higher electronegativities.
Group (I), (II) and (III) are metals while Group (IV), (V), (VI) , (VII), (VIII) and Group 0 are non-metal. Sodium fall on Group (I) while sulfur fall on (VI).
Above picture is from :
http://hyperphysics.phy-astr.gsu.edu/hbase/pertab/metal.html
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